Binary supramolecular adduct based upon trimeric perfluoro-ortho-phenylenemercury and 4-chlorobenzaldehyde: Enumerating the strength of perfluorophenyl-perfluorophenyl interactions
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- 作者：Steven P. Fishera ; Herman R. Krueger Jr.b ; Ryan H. Groenemanb ; Eric W. Reinheimera ; eric.reinheimer@gmail.com" class="auth_mail" title="E-mail the corresponding author
- 关键词：Supramolecular chemistry ; Trimeric perfluoro-ortho-phenylenemercury ; Perfluorotribenzo[b ; e ; h][1 ; 4 ; 7]trimercuronin ; Perfluorophenyl&ndash ; perfluorophenyl interaction ; Computational chemistry
- 刊名：Journal of Molecular Structure
- 出版年：2016
- 出版时间：5 January 2016
- 年：2016
- 卷：1103
- 期：Complete
- 页码：140-144
- 全文大小：893 K
文摘
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Molecular complex containing trimeric perfluoro-ortho-phenylenemercury and 4-chlorobenzaldehyde was realized.
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Perfluorophenyl–perfluorophenyl interaction energies were determined by Density Functional Theory.
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X-ray diffraction and IR spectroscopy was used to investigate the molecular complex.