Synthesis, optical and electrochemical properties of novel phenyl- and phenoxy-substituted subphthalocyanines
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- 作者：Tatiana V. Dubininaa ; b ; 1 ; dubinina.t.vid@gmail.com" class="auth_mail" title="E-mail the corresponding author ; Marina M. Osipovaa ; Anton V. Zasedatelevc ; Vitaly I. Krasovskiic ; d ; Nataliya E. Borisovaa ; Stanislav A. Trashinb ; 1 ; Larisa G. Tomilovaa ; b ; 1 ; tom@org.chem.msu.ru" class="auth_mail" title="E-mail the corresponding author ; Nikolay S. Zefirova
- 关键词：Subphthalocyanine ; Phthalocyanine analogues ; Luminescence ; UV&ndash ; Vis spectroscopy ; Electrochemistry ; Non-linear optics
- 刊名：Dyes and Pigments
- 出版年：2016
- 出版时间：May 2016
- 年：2016
- 卷：128
- 期：Complete
- 页码：141-148
- 全文大小：1271 K
文摘
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Novel phenyl- and phenoxy-substituted subphthalocyanines were synthesized.
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The influence of a heavy atom effect on intersystem crossing was demonstrated.
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Picosecond lifetimes of high-lying excited states were established.
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Higher electron-donating ability of phenyl- compared to phenoxy groups was shown.