Thermo-responsive self-assembled metallomicelles accelerate asymmetric sulfoxidation in water
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- 作者：Yaoyao Zhanga ; b ; Rong Tana ; b ; yiyangtanrong@126.com" class="auth_mail" title="E-mail the corresponding author ; Guangwu Zhaoa ; b ; Xuanfeng Luoa ; b ; Chen Xinga ; b ; Donghong Yina ; b ; c ; yindh@hunnu.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Thermo-responsive ; Micellar catalysis ; Chiral salen TiIV complex ; Asymmetric sulfoxidation ; Water
- 刊名：Journal of Catalysis
- 出版年：2016
- 出版时间：March 2016
- 年：2016
- 卷：335
- 期：Complete
- 页码：62-71
- 全文大小：1664 K
文摘
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Thermoresponsive surfactant-type chiral salen TiIV catalysts were developed.
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The catalysts self-assembled in water to form metallomicelles with different morphologies.
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Asymmetric sulfoxidation was efficiently conducted in water with the metallomicelles.
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Outstanding activity and selectivity were achieved as a result of the “micellar catalysis”.
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The catalyst can be easily recovered for efficient reuse via thermocontrolled separation.