Molybdenum-catalyzed asymmetric sulfoxidation with hydrogen peroxide and subsequent kinetic resolution, using an imidazolium-based dicarboxylate compound as chiral inductor
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- 作者：Carlos J. Carrasco ; Francisco Montilla montilla@us.es" class="auth_mail" title="E-mail the corresponding author ; Agustí ; n Galindo ; galindo@us.es" class="auth_mail" title="E-mail the corresponding author
- 关键词：Molybdenum ; Asymmetric catalysis ; Oxidation ; Kinetic resolution
- 刊名：Catalysis Communications
- 出版年：2016
- 出版时间：5 September 2016
- 年：2016
- 卷：84
- 期：Complete
- 页码：134-136
- 全文大小：274 K
文摘
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An imidazolium-based dicarboxylate, derived from l-valine, was used as chiral inductor.
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This inductor was effective in the Mo-catalyzed asymmetric sulfoxidation.
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Good yields of chiral sulfoxide were obtained by kinetic resolution.
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Better reaction times were observed than in other related Mo-complexes.