The influence of p-type Mn3O4 nanostructures on the photocatalytic activity of ZnO for the removal of bromo and chlorophenol in natural sunlight exposure
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Implantation of p-type Mn3O4 on the surface of ZnO enhance the photocatalytic activity in natural sunlight.

The charge transfer synergy between the p-type Mn3O4 and n-type ZnO conformed the generation of ROS in the system.

Superoxide anion (O2●−) radicals are the major contributors in removal process.

Priority interaction of ROS with the substrates rather than intermediates.

Cl and Br serves as facilitators in the degradation process.

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