Isobaric heat capacity (Cp) measurements of supercritical fluids using flow calorimetry: equipment design and experimental validation with carbon dioxide, methanol, and carbon dioxide-methanol mixtures
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- 作者：Mitchell P.E. Ishmael mpi4@cornell.edu" class="auth_mail" title="E-mail the corresponding author ; Maciej Z. Lukawski mzl8@cornell.edu" class="auth_mail" title="E-mail the corresponding author ; Jefferson W. Tester ; jwt54@cornell.edu" class="auth_mail" title="E-mail the corresponding author
- 关键词：Calorimeter ; Heat capacity ; Critical point ; Carbon dioxide ; Methanol ; CO2 ; Supercritical
- 刊名：The Journal of Supercritical Fluids
- 出版年：2016
- 出版时间：November 2016
- 年：2016
- 卷：117
- 期：Complete
- 页码：72-79
- 全文大小：1134 K
文摘
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Flow calorimeter with a large temperature, pressure, and composition range.
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Cp measurements of supercritical carbon dioxide.
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Cp measurements of methanol and carbon dioxide-methanol mixtures.
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Basic ±1% accuracy in isobaric heat capacity over the entire experimental region.