Materials modification and die design for minimizing internal melt distortions of glass fiber/PP co-extrudates

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• 作者：Sarun Rungruangsuparat^a ; Somjate Patcharaphun^b ; ^{fengsjpc@ku.ac.th} ; Narongrit Sombatsompop^a ; ^{narongrit.som@kmutt.ac.th}
• 关键词：Co-extrusion ; Internal melt fracture ; Polypropylene ; Rheological properties ; Glass fibers
• 刊名：Polymer Testing
• 出版年：2017
• 出版时间：February 2017
• 年：2017
• 卷：57
• 期：Complete
• 页码：184-191
• 全文大小：2480 K
• 卷排序：57

文摘

The rheological properties and internal melt fracture of polypropylene (PP) composites during co-extrusion were investigated. Neat polypropylene was used as a skin layer and polypropylene filled with short glass fibers at various concentrations (0–30 wt%) was used as a core layer. It was found that the pressure drop (ΔP  ) increased with increasing shear rate of the core layer (γ˙core) and short glass fiber content, whereas the extrudate swell of co-extrudate decreased with increasing fiber content. The internal melt fracture in a helical form was found in the core layer of co-extrudate, this being quantitatively measured by the height (amplitude, A) and the width (period, λ) of the helical distortion. The internal melt fracture tended to increase with increasing amount of glass fiber and shear rate of the core layer. Two methods were employed for eliminating the internal melt fracture of the co-extruded PP composites:, addition of lubricants and die geometry design. The addition of silicone oil and hexagonal boron nitride (h-BN) could not moderate the melt fracture. Elimination of the internal melt fracture could be successfully accomplished by the use of a cone tapered die without capillary length.