Nanofluorides

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• 作者：Pavel P. Fedorov  ; ;   ; ^{ppf@lst.gpi.ru} ; Anna A. Luginina ; Sergei V. Kuznetsov ; Vyacheslav V. Osiko
• 关键词：Inorganic fluorides ; Nanofluorides ; Nanoparticles ; Nanocomposites ; Up-conversion
• 刊名：Journal of Fluorine Chemistry
• 出版年：2011
• 出版时间：December 2011
• 年：2011
• 卷：132
• 期：12
• 页码：1012-1039
• 全文大小：2374 K

文摘

The present review article covers major aspects of inorganic chemistry of nanofluorides, including methods of their synthesis (thermolysis of the precursors, co-precipitation from solutions, reversed micelle technique, hydro- and solvo-thermal techniques, sol¨Cgel method, etc.), nanochemical effects (enhanced chemical activity, self-organization and self-assembly, non-classical mechanism of the single crystal growth, synthesis of non-equilibrium phases), targeted preparation of 1D, 2D, and 3D nanostructures, surface modification of the nanoparticles, fluoride nanocomposites (glass- and nano-ceramics) as well as applications of nanofluorides.