We have fabricated p-n junctions using a combination of p- and n-type thiophene/phenylene co-oligomer (TPCO) thin films and applied them to organic light-emitting diodes (OLEDs). We made two types of devices using the different p-type TPCOs. Both the devices showed current-injected light emissions and high rectification ratios (~ 102-104). The one type of the devices produced brighter surface emissions and higher external quantum efficiencies (0.17 % ) than the other. The results indicated that the p-n junction comprising layered TPCOs showed good functionality.