Highly efficient electrocatalytic oxidation of formic acid on palladium nanoparticles-graphitic carbon nitride composite

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• 作者：Tanmay Bhowmik ; Manas Kumar Kundu ; Sudip Barman ; ^{sbarman@niser.ac.in}
• 关键词：Graphitic carbon-nitride ; Palladium nanoparticle ; Formic acid oxidation ; Electrocatalyst ; Synergistic interaction
• 刊名：International Journal of Hydrogen Energy
• 出版年：2017
• 出版时间：5 January 2017
• 年：2017
• 卷：42
• 期：1
• 页码：212-217
• 全文大小：1259 K
• 卷排序：42

文摘

Catalytic activity of PdNPs/CNx towards FAO is better than commercial Pt/C and Pd/C. Mass activity of PdNPs/CNx is 7.6 and 36 times of Pd/C and Pt/C at 0.4 V in RHE. PdNPs/CNx has higher stability towards FAO than commercial Pt/C and Pd/C. Strong interaction between Pd-NPs, g-CNx lowering Rct which attributed to superior FAO.