Synthesis and antimicrobial activities of copper(II) complexes of N(4),N(11)-dimethyl (LBZ & LCZ) and N(4)-monomethyl (LCZ1)-3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane. Crystal and molecular structure
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- 作者：Tapashi G. Roya ; tapashir57@gmail.com" class="auth_mail ; Saroj K.S. Hazaria ; Hazrat A. Miaha ; Suman K.D. Guptaa ; Prashun G. Roya ; Ulrich Behrensb ; Dieter Rehderb
- 关键词：N-pendent macrocyclic ligands ; Copper ; Spectroscopic methods ; X-ray crystallography ; Antimicrobial activities
- 刊名：Inorganica Chimica Acta
- 出版年：1 May 2014
- 年：2014
- 卷：415
- 期：Complete
- 页码：124-131
- 全文大小：615 K
文摘
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A novel biologically relevant N-pendent cyclic tetraaza ligand was prepared.
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Cu(II) complexes of cyclic tetraaza ligands were synthesized and characterized.
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X-ray analysis revealed square planar coordination geometry for [CuL](ClO4)2.
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Some of the complexes adapt varying geometry in different solvents.
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Some of the complexes exhibit antifungal and antibacterial activity.