Metal-binding motifs of alkyl and aryl phosphinates; versatile mono and polynucleating ligands

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• 作者：Innis Carson ; Mary R. Healy ; Euan D. Doidge ; Jason B. Love ; Carole A. Morrison ; Peter A. Tasker ; ^{p.a.tasker@ed.ac.uk}
• 刊名：Coordination Chemistry Reviews
• 出版年：2017
• 出版时间：15 March 2017
• 年：2017
• 卷：335
• 期：Complete
• 页码：150-171
• 全文大小：7571 K
• 卷排序：335

文摘

Phosphinates are extraordinarily versatile ligands. Ten different binding modes are found in crystalline metal complexes. Complexes are formed with metals in all parts of the periodic table. H-bond formation in the outer sphere often defines speciation. Their coordination chemistry underpins uses in widely ranging applications.