Crystallite size effect in the sulfidation of ZnO by H2S: Geometric and kinetic modelling of the transformation
详细信息 查看全文
- 作者：C¨¦line Bab¨¦ ; Melaz Tayakout-Fayolle ; Christophe Geantet ; Michel Vrinat ; G¨¦rard Bergeret ; Thierry Huard ; Delphine Bazer-Bachi
- 关键词：Desulfurization ; Zinc oxyde sulfidation ; Kinetics modelling ; Breakthrough curve ; Sulfur removal ; Size effect
- 刊名：Chemical Engineering Science
- 出版年：2012
- 出版时间：12 September, 2012
- 年：2012
- 卷：82
- 期：Complete
- 页码：73-83
- 全文大小：1228 K
文摘
Hydrogen sulfide capture is an important technological challenge in energy and fuel industries, and reactive adsorption over zinc oxide is considered as a highly efficient one. This type of desulfurizing process is often proposed in the literature for the treatment of gas such as coal derived fuel gas, biogas or syngas. We investigated the capture of H2S by ZnO, in a continuous flow unit, using several powders having different crystallite sizes and obtained by sintering of a commercial product. From the breakthrough curves obtained by means of sulfidation experiments performed on a fixed bed reactor of sorbent crystallites and crystallographic considerations, a layer by layer representation of the crystallites sulfidation was established and demonstrated that the sulfidation was limited for large crystallites, despite there was no thermodynamic limitation. A modelling of the breakthrough curves was performed using a geometrical model of the ZnO sulfidation layer per layer of the crystallite, including a variable diffusion coefficient, providing a good correlation between experimental and calculated data.