Alternatives binary and ternary blends and its effects on stability of soybean biodiesel contaminated with metals

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• 作者：Marina Comin^a ; Ana C.D. de Souza^a ; Ana C. Roveda^a ; Silvia S. Yahagi^a ; Luiz H. de Oliveira^a ; Mariana S. Amaral^a ; Cinthia A.A. Silva^b ; Antonio R. Fiorucci^b ; Roberto S. Gomes^c ; Anderson R.L. Caires^d ; Magno A.G. Trindade^a ; ^{magnotr@gmail.com}
• 关键词：Biofuels ; Thermal stability ; Alizarin ; Metal deactivator ; Alternative additive
• 刊名：Fuel
• 出版年：2017
• 出版时间：1 March 2017
• 年：2017
• 卷：191
• 期：Complete
• 页码：275-282
• 全文大小：779 K
• 卷排序：191

文摘

The effect of metal contaminants Fe(III), Ni(II), Mn(II), Co(II) and Cu(II) on the stability of soybean biodiesel (SB) was studied in the presence and absence of alternatives binary and ternary blends. The blends were composed by alizarin (ALZ), as the alternative additive, tert-butylhydroquinone (TBHQ) as well as the citric acid (CA) and their effectiveness on SB (B100) stability was evaluated via induction period to measure the synergistic effect, following by acid value and kinematic viscosity to measure the accelerate thermal oxidation. We find that even in small concentrations, the metals were enough to degrade SB in the absence of additives, in which Cu(II) showed the highest catalytic effect. However, we show that target blends, even at low concentrations, have great impact on SB stability compared to the effects provided by the individual additives (at highest concentration). This finding influence directly in the reduction of the final costs due to reduction around 70% of the total amount of additives used to stabilize the biodiesel.