Redox cycling in the activation of peroxides by iron porphyrin and manganese complexes. ‘Catching’ catalytic active intermediates
详细信息 查看全文
- 作者：Maria Oszajcaa ; Alicja Frankeb ; Małgorzata Brindella ; Grażyna Stochela ; stochel@chemia.uj.edu.pl" class="auth_mail" title="E-mail the corresponding author ; Rudi van Eldika ; b ; rudi.vaneldik@fau.de" class="auth_mail" title="E-mail the corresponding author
- 关键词：t-BuOOH ; tert-butyl hydroperoxide ; CumOOH ; cumyl hydroperoxide ; MPPH ; 2-methyl-1-phenylpropan-2-yl hydroperoxide ; TDFPPS ; meso-tetrakis(2 ; 6-difluoro-3-sulfonatophenyl)porphyrin ; TDCPPS ; meso-tetrakis(2 ; 6-dichloro-3-sulfonatophenyl)porphyrin ; TMPyP ; meso-tetrakis(N-methylpyridin-4-ylium)porphyrin ; TMPDS ; meso-tetrakis(2 ; 5-disulfonatomesityl)porphyrin ; TMPS ; meso-tetrakis(2 ; 4 ; 6-trimethyl-3-sulfonatophenyl)porphyrin ; m-CPBA ; m-chloroperoxybenzoic acid ; PhIO ; iodosobenzene ; Por ; porphyrin ; TBAOH ; te
- 刊名：Coordination Chemistry Reviews
- 出版年：2016
- 出版时间：1 January 2016
- 年：2016
- 卷：306
- 期：part_P2
- 页码：483-509
- 全文大小：3273 K
文摘
- •
Generation and reactivity of Compound I and II models under aqueous conditions.
- •
Iron porphyrin models for Compounds 0, I, and II in P450 model oxygenation reactions.
- •
Experimental and theoretical studies as a source of mechanistic information on the reactivity of heme enzyme mimics.
- •
Manganese complexes as catalysts for the oxidative degradation of organic dyes.