Hydrothermal synthesis of plate-like sodium niobate particles

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• 作者：Yao Lu ; Tomoaki Karaki ; ^{chen@pu-toyama.ac.jp" class="auth_mail" title="E-mail the corresponding author} ; Tadashi Fujii
• 关键词：D. Niobates ; Hydrothermal synthesis ; Plat-like
• 刊名：Ceramics International
• 出版年：2015
• 出版时间：July 2015
• 年：2015
• 卷：41
• 期：supp_S1
• 页码：S174-S179
• 全文大小：1044 K

文摘

Sodium niobate (NaNbO₃) particles with perovskite structure and plate-like morphology were successfully prepared through calcining the plate-like hexagonal NaNbO₃ particles that were synthesized by hydrothermal method. A single phase of hexagonal NaNbO₃ was obtained under the condition of 200 °C and [OH⁻]=1.0 mol/L, and the particle size is about 15 μm in diameter and 2 μm in thickness. Through researching the effects of reaction temperature and concentration of OH⁻, the best condition to prepare the hexagonal NaNbO₃ plate-like particles was investigated. After further calcination treatment, the particles were completely transformed into perovskite structure with the orthorhombic unit cell without morphology change. Compared with the traditional high temperature molten salt method, this work provides a simpler way to prepare NaNbO₃ template for templated grain growth (TGG) or reactive templated grain growth (RTGG) texture techniques.