Diruthenium tetracarbonyl sawhorse complexes bearing N-heterocylic carbene and phosphine ligands: Synthesis, structural characterization, and catalytic activity
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- 作者：Thomas N. Rohrabaugh Jr.a ; Joshua C. Doverspikea ; Steven J. Geibb ; Evan D. Sawyera ; Mitchell R. Stibbarda ; Thomas J. Malosha ; malosh@pitt.edu" class="auth_mail" title="E-mail the corresponding author
- 关键词：Ruthenium ; Dinuclear complexes ; Catalysis ; Carbene ligands ; Phosphine ligands ; Carboxylato bridges
- 刊名：Journal of Organometallic Chemistry
- 出版年：2016
- 出版时间：15 January 2016
- 年：2016
- 卷：802
- 期：Complete
- 页码：1-8
- 全文大小：799 K
文摘
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The first diruthenium tetracarbonyl sawhorse NHC adduct is reported.
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An assay of catalytic ability, mild conditions, reveals a distinctly active complex.
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DFT calculations were performed to support experimental results.
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Phosphine cone angles, as achieved in the solid-state, have been calculated.