The bridging azido ligand as a central 鈥減layer鈥?in high-nuclearity 3d-metal cluster chemistry
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- 作者：Albert Escuera ; albert.escuer@ub.edu" class="auth_mail ; albert.escuer@qi.ub.edu" class="auth_mail ; Jordi Estebana ; Spyros P. Perlepesb ; perlepes@upatras.gr" class="auth_mail ; Theocharis C. Stamatatosc
- 关键词：Azido ligand ; 3d-cluster chemistry ; Magnetic properties ; Structural analysis ; SMM response
- 刊名：Coordination Chemistry Reviews
- 出版年：1 September 2014
- 年：2014
- 卷：275
- 期：Complete
- 页码：87-129
- 全文大小：10696 K
文摘
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Azido clusters for d-elements, with nuclearity equal to or larger than four, have been reviewed.
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Structural and synthetic features are described.
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Azide ligand plays a key role to promote ferromagnetic interactions and to generate systems with SMM response.