Reversible thermochromism via hydrogen-bonded cocrystals of polydiacetylene and melamine
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- 作者：Juan Guoa ; 1 ; Kaiyu Fua ; 1 ; Zhongbo Zhangb ; Lianyun Yangb ; Yu-Chen Huangc ; Ching-I. Huangc ; Lei Zhub ; lxz121@case.edu" class="auth_mail" title="E-mail the corresponding author ; Daoyong Chena ; chendy@fudan.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Polydiacetylene ; Melamine ; Cocrystal ; Reversible thermochromism ; Non-covalently connected micelle
- 刊名：Polymer
- 出版年：2016
- 出版时间：22 November 2016
- 年：2016
- 卷：105
- 期：Complete
- 页码：440-448
- 全文大小：2635 K
文摘
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10,12-pentacosadiynoic acid (DA) and melamine (MA) form non-covalently connected micelles (NCCMs) in aqueous solution.
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Annealing of the DA/MA NCCMs at 65 °C leads to well-organized cocrystals.
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Topochemical polymerization of the DA/MA cocrystals results in reversible thermochromism.