Synthesis, spectroscopic and structural characterization of the pentacoordinate high-spin Fe (III) isothiocyanate “picket fence” porphyrin complex

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• 作者：Nasri ; Habib ; Debbabi ; Mongi
• 关键词：porphyrin ; iron(III) complex ; isothiocyanatecomplex ; high-spin Fe(III) ; molecular structure
• 刊名：Polyhedron
• 出版年：1998
• 出版时间：September 30, 1998
• 年：1998
• 卷：17
• 期：20
• 页码：3607-3612
• 全文大小：267 K

文摘

The preparation and the characterization of the (isothiocyanato) (α,α,α,α-tetrakis (o-pivalamidophenyl) porphinato) iron (III) complex is described. The synthesis procedure utilizes the crown ether 18-C-6 to solubilize potassium thiocyanate. ¹H NMR and EPR data of the isolated product are in accordance with a high-spin (S