Structural and photophysical characterization of a tin(IV) porphyrin-rhenium(I)(diimine) conjugate
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- 作者：Paolo Caviglia ; Gabriele Balduccia ; Ennio Zangrandoa ; Nicola Demitrib ; Agnese Amatic ; Maria Teresa Indellic ; ; Elisabetta Iengoa ;
- 关键词：Tin(IV) porphyrin ; Re(I)(diimine) complexes ; Axial coordination ; X-ray crystal structures ; Time-resolved techniques ; Energy transfer
- 刊名：Inorganica Chimica Acta
- 出版年：2016
- 出版时间：1 January 2016
- 年：2016
- 卷：439
- 期：Complete
- 页码：61-68
- 全文大小：1310 K
文摘
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A novel robust Sn-porphyrin–rhenium(I)(diimine) conjugate is reported.
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A thorough solution and X-ray structural characterization of the conjugate is given.
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Sensitization of the 3*Sn-porphyrin, after excitation of the Re units, is observed.