Excellent performance of TiO2(B) nanotubes in selective transesterification of DMC with phenol derivatives
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- 作者：Yuan Gaoa ; Zhenhuan Lia ; Zhenhuanli1975@aliyun.com" class="auth_mail" title="E-mail the corresponding author ; Kunmei Sub ; Bowen Chenga
- 关键词：TiO2(B) nanotubes ; Anatase TiO2 ; Dimethyl carbonate ; Transesterification ; Methylation
- 刊名：Chemical Engineering Journal
- 出版年：2016
- 出版时间：1 October 2016
- 年：2016
- 卷：301
- 期：Complete
- 页码：12-18
- 全文大小：1261 K
文摘
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TiO2(B) showed higher activity in transesterification of DMC with phenol derivatives.
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TG–MS and DRIFTS characterized DMC desorption, adsorption and activation mechanism.
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TiO2(B) nanotubes has higher Ti3+ content than anatase TiO2.
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Activity was related with higher Ti3+ content, surface area and structure defects.