Total synthesis of (±)-dihydroprotolichesterinic acid and formal synthesis of (±)-Roccellaric acid by radical cyclisation of an epoxide. Using a transition-metal radical source

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• 作者：Mandal ; Pijus Kumar ; Roy ; Subhas Chandra
• 关键词：Dihydroprotolichesterinic acid ; Roccellaric acid ; radical cyclisation ; epoxide ; transition matal
• 刊名：Tetrahedron
• 出版年：1999
• 出版时间：September 10, 1999
• 年：1999
• 卷：55
• 期：37
• 页码：11395-11398
• 全文大小：228 K

文摘

A short and efficient total synthesis of (±)-Dihydroprotolichesterinic acid (1) and Formal synthesis of (±)-Roccellaric acid (2) has been acheived by radical cyclisation of epoxide using a transition metal radical source.