Fluorescent probe encapsulated hydrogel microsphere for selective and reversible detection of Hg2+
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- 关键词：Hydrogel ; Fluorescence probe ; PEG-DA ; Microfluidic ; Hg2+
- 刊名：Journal of Luminescence
- 出版年：2017
- 出版时间：March 2017
- 年：2017
- 卷：183
- 期：Complete
- 页码：212-216
- 全文大小：984 K
- 卷排序：183
文摘
We developed a simple and sensitive hydrogel sensor in the form of microspheres by using fluorescence probe encapsulated within a hydrogel matrix for the detection of Hg2+. The traditional fluorescence probes suspended in solution are not transportable and recoverable. To overcome these disadvantages, we devised poly(ethylene glycol) diacrylate-based hydrogel microspheres in which fluorescence probe (R19S) was embedded at high density. The functionalized hydrogel microspheres were prepared by combining a microfluidic device with UV light. The hydrogel microspheres-based sensor exhibited good selectivity to Hg2+ among various metal ions and high sensitivity with a detection limit of 90 nM. Furthermore, after binding with Hg2+, the R19S encapsulated hydrogel microspheres can be separated from testing samples easily and treated with the solution containing KI to remove Hg2+ and realize reusable detection. The current work may offer a new method for Hg2+ recognition with a more efficient manner.