Triterpenoid saponins and sapogenin lactones from Albizia gummifera

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• 作者：Debella ; Asfaw ; Haslinger ; Ernst ; Schmid ; Martin G. ; Bucar ; Franz ; Michl ; Gü ; nter ; Abebe ; Dawit ; et. al.
• 关键词：Albizia gummifera (C.A. Smith) ; Mimosaceae ; Machaerinic acid lactone glycosides ; A-homo-3a-oxa-olean-12-en-28-oic acid ; Oleanolic acid glycosides ; Stigmasterol glycoside ; Stem bark
• 刊名：Phytochemistry
• 出版年：2000
• 出版时间：April, 2000
• 年：2000
• 卷：53
• 期：8
• 页码：885-892
• 全文大小：206 K

文摘

The structures of two new monodesmosidic and bisdesmosidic triterpenoid saponins (1 and 2) and the known compound Δ⁵-stigmasterol-3-O-β-D-glucopyranoside (3) as well as two new oleanane type triterpene lactone glycosides 4, 5 and a new sapogenin lactone 6 isolated from the stem bark of Albizia gummifera C.A. Smith (Mimosaceae) have been elucidated as 3-O-{β-D-glucopyranosyl(1→2)-[α-L-arabinopyranosyl(1→6)]-β-D-glucopyranosyl}-oleanolic acid (1), β-D-glucopyranosyl(1→2)-β-D-glucopyranosyl 3-O-{β-D-glucopyra-nosyl(1→2)-[α-L-arabinopyranosyl(1→6)]-β-D-glucopyranosyl}-oleanolate (2), 3β-{O-D-glucopyranosyl-(1→2)-[O-α-L-arabinopyranosyl(1→6)]β-D-glucopyranosyloxy}-machaerinic acid γ-lactone (4), 3β-O-β-D-glucopyranosiduronic acid (1→2)-β-D-glucopyranosyloxy]-machaerinic acid γ-lactone (5), and A-homo-3a-oxa-5β-olean-12-en-3-one-28-oic acid (6), respectively. The complete assignment of the ¹H and ¹³C resonances of 1, 2, 4 and 6 and of the peracetate of 5 were achieved by means of 2D-NMR studies.