Protein Radicals in Myoglobin Dimerization and Myoglobin-Catalyzed Styrene Epoxidation

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• 作者：Tschirret-Guth ; Richard A. ; de Montellano ; Paul R. Ortiz
• 刊名：Archives of Biochemistry and Biophysics
• 出版年：1996
• 出版时间：November 1, 1996
• 年：1996
• 卷：335
• 期：1
• 页码：93-101
• 全文大小：178 K

文摘

Two mechanisms have been identified for the H₂O₂-dependent epoxidation of styrenes by sperm whale myoglobin (Mb) [S. Rao, A. Wilks, and P.R. Ortiz de Montellano,J. Biol. Chem.268, 803–908 (1993)]: (a) ferryl (Fe^IV