Facile synthesis of g-Cub>3ub>Nub>4ub>/BiVOub>4ub> heterojunctions with enhanced visible light photocatalytic performance
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文摘
A g-Cub>3ub>Nub>4ub>/BiVOub>4ub> composite photocatalyst with enhanced photocatalytic activity and photoelectrochemical (PEC) performance was fabricated via a simple synthesis method with BiVOub>4ub> nanofibers as starting material. The materials were characterized with different techniques such as X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), UV–vis diffuse reflectance spectroscopy (DRS), Fourier transform infrared spectroscopy (FT-IR), Nub>2ub> absorption–desorption isotherm (BET) and photoluminescence spectroscopy (PL). The results showed that this synthesis method is effective to make a composite. The photocatalytic evaluation indicates that the photocatalytic activity of the g-Cub>3ub>Nub>4ub>/BiVOub>4ub> photocatalyst for methylene blue (MB) was about 8 and 7 times higher than that of pure BiVOub>4ub> and g-Cub>3ub>Nub>4ub>, respectively. This should be due to the enhanced light harvesting ability and to the effective electron transfer during the photocatalytic reaction.

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