Oxidative-addition of germanium-hydrogen bonds to triosmium centers: Reactions of Os3(CO)10(μ-dppm) and Os3(CO)8(μ3-Ph2PCH2P(Ph)C6H4)(μ-H) with Ph3GeH
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- 作者：Mohd. Rezaul Haquea ; Md. Jakir Hossaina ; Ahibur Rahamana ; Shishir Ghosha ; Shariff E. Kabira ; skabir_ju@yahoo.com" class="auth_mail" title="E-mail the corresponding author ; Graeme Hogarthb ; Derek A. Tocherc
- 关键词：Triosmium clusters ; Carbonyls ; Triphenylgermanium hydride (Ph3GeH) ; Bis(diphenylphosphino)methane (dppm) ; Oxidative-addition of Ge‒H bond ; X-ray structures
- 刊名：Journal of Organometallic Chemistry
- 出版年：2016
- 出版时间：15 June 2016
- 年：2016
- 卷：812
- 期：Complete
- 页码：240-246
- 全文大小：824 K
文摘
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Oxidative-addition of Ge‒H bond to triosmium clusters.
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Reaction of Os3(CO)10(μ-dppm) with Ph3GeH.
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Reaction of Os3(CO)8(μ3-Ph2PCH2P(Ph)C6H4)(μ-H) with Ph3GeH.
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Synthesis and structure of 46-electron Os3(CO)7(GePh3)(μ3-Ph2PCH2P(Ph)C6H4)(μ-H)2.