Enthalpies of solution, enthalpies of fusion and enthalpies of solvation of polyaromatic hydrocarbons: Instruments for determination of sublimation enthalpy at 298.15 K
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- 作者：Boris N. Solomonov ; boris.solomonov@ksu.ru" class="auth_mail" title="E-mail the corresponding author ; Mikhail A. Varfolomeev ; Ruslan N. Nagrimanov ; Timur A. Mukhametzyanov ; Vladimir B. Novikov
- 关键词：Polycyclic aromatic hydrocarbons ; Solution calorimetry ; Enthalpy of solvation ; Enthalpy of solution ; Enthalpy of fusion ; Enthalpy of sublimation
- 刊名：Thermochimica Acta
- 出版年：2015
- 出版时间：20 December 2015
- 年：2015
- 卷：622
- 期：Complete
- 页码：107-112
- 全文大小：194 K
文摘
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Solution enthalpies of aromatic hydrocarbons were measured at 298.15 K.
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Solution enthalpy of aromatic hydrocarbons in benzene is equal to their fusion enthalpy.
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Method for calculation of solvation enthalpy of aromatic hydrocarbons was proposed.
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Approach for estimation of aromatic hydrocarbons sublimation enthalpy was developed.
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Obtained sublimation enthalpies coincide well with the recommended literature data.