A new three-dimensional Cu(II) coordination polymer with triaminoguanidin building blocks
详细信息 查看全文
- 作者：Aksana Zharkouskaya ; Helmar Gö ; rls ; Gavin Vaughan and Winfried Plass
- 关键词：Coordination polymer ; Copper(II) complex ; Crystal structure ; Magnetic properties ; Self-assembly
- 刊名：Inorganic Chemistry Communications
- 出版年：2005
- 出版时间：December 2005
- 年：2005
- 卷：8
- 期：12
- 页码：1145-1148
- 全文大小：369 K
文摘
The reaction between the tris(2-hydroxybenzylidene)triaminoguanidin hydrochloride (H6L)Cl and copper(II) chloride in the presence of triethylamine leads to a three-dimensional coordination polymer with two interpenetrating (10,3)-a networks of opposite chirality. Magnetic studies revealed strong antiferromagnetic coupling between copper ions of the spin frustrated trinuclear building unit.