Polyaniline All Solid-State Pseudocapacitor: Role of Morphological Variations in Performance Evolution

详细信息    查看全文

• 作者：Sonia Grover ; Shubhra Goel ; Ram Bhagat Marichi ; Vikrant Sahu ; Gurmeet Singh ; ^{gurmeet123@yahoo.co.in" class="auth_mail" title="E-mail the corresponding author} ; Raj Kishore Sharma ; ^{drrajksharma@yahoo.co.in" class="auth_mail" title="E-mail the corresponding author}
• 关键词：polyaniline ; self-assembly ; morphology ; nanotube ; solid-state supercapacitors
• 刊名：Electrochimica Acta
• 出版年：2016
• 出版时间：1 April 2016
• 年：2016
• 卷：196
• 期：Complete
• 页码：131-139
• 全文大小：2782 K

文摘

We report a facile soft-template approach to develop polyaniline (PANI) nanostructures in various morphologies (nanotube, nanorod, nanosphere and nanosheet) by triggering the amount of N-cetyl-N,N,N-trimethyl trimethylammonium bromide (CTAB) surfactant. The possible mechanistic pathways for the formation of PANI structures explain the occurrence of different growth patterns and the aggregation archetype of monomeric units in undertaken polymerization reaction. Brunauer-Emmett-Teller measurements reveal that PANI nanotube possess highest surface area (33.8 m² g⁻¹) due to availability of hollow central portion, while the 1D ordered arrangement of aniline units significantly increase its conductivity (0.92 mS cm⁻¹). Pseudocapacitive performance of these morphologically different PANI electrodes in all solid-state supercapacitor cells is studied using a solid electrolyte (PVA/H₂SO₄). Electrochemical attributes of solid-state pseudocapacitor cells clearly indicate that nanotube exhibits highest specific capacitance (367 F g⁻¹ at 5 mV s⁻¹) among all PANI forms, and can be cycled successfully up to continuous 1000 GCD cycles retaining more than 91.5% capacitance in PVA/H₂SO₄ electrolyte at high current density of 5 A g⁻¹.