A new application of Salamo-type bisoximes: As a relay-sensor for Zn2+/Cu2+ and its novel complexes for successive sensing of H+/OH∿/sup>
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- 作者：Wen-Kui Donga ; dongwk@126.com" class="auth_mail" title="E-mail the corresponding authorAuthor Vitae ; Xia-Liang LiaAuthor Vitae ; Li WangaAuthor Vitae ; Yang ZhangaAuthor Vitae ; Yu-Jie Dingb ; yujieding123@163.com" class="auth_mail" title="E-mail the corresponding authorAuthor Vitae
- 关键词：Salamo-type bisoxime ; Zn2+/Cu2+ relay&ndash ; sensor ; Displacement ; Crystal structure
- 刊名：Sensors & Actuators: B. Chemical
- 出版年：2016
- 出版时间：28 June 2016
- 年：2016
- 卷：229
- 期：Complete
- 页码：370-378
- 全文大小：2719 K
文摘
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A single-armed Salamo-type bisoxime H3L has been designed and synthesized firstly.
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H3L can be used as a relay–sensor for relay recognition of Zn2+ and Cu2+ with high selectivity and sensitivity.
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The complexes behave successive sensing of H+/OH− through fluorescence intensity increasing (ON) and decreasing (OFF).
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Two novel Zn2+ and Cu2+ dinuclear complexes have been synthesized and determined by X-ray crystallographic analysis.