Solid state coordination chemistry of the oxofluorovanadium–diphosphonate system in the presence of Cu(II)–tetrapyridylpyrazine complex cations: The crystal structures of [{Cu2
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- 作者：Wayne Ouellette ; Vladimir Golub ; Charles J. O’ ; Connor ; Jon Zubieta
- 关键词：Bimetallic oxides ; Organic– ; inorganic hybrid materials ; Vanadium organophosphonates ; Copper– ; tetrapyridylpyridine components ; Oxyfluorovanadates
- 刊名：Journal of Solid State Chemistry
- 出版年：2007
- 出版时间：September 2007
- 年：2007
- 卷：180
- 期：9
- 页码：2500-2509
- 全文大小：1082 K
文摘
The hydrothermal reactions of V2O5, Cu(CH3CO2)2·H2O, tetrapyridylpyrazine (tpyprz), HF and the appropriate diphosphonic acid yielded a series of compounds of the JRY-1&_mathId=mml4&_user=10&_cdi=6922&_rdoc=15&_acct=C000050221&_version=1&_userid=10&md5=19525d6bc19e3bd85fb86f56de0d4ac5"">![]()
family of materials. The structure of [{Cu2(tpyprz)(H2O)2}V4F6O6(HO3PCH2PO3)2] (1) is one-dimensional, constructed from mixed valence ![]()
clusters linked through {Cu2(tpyprz)(H2O)2}4+ rods. The two-dimensional [{Cu2(tpyprz)(H2O)2}V4F6O6(O3PCH2CH2PO3)] (2) is constructed from ![]()
chains crosslinked by {Cu2(tpyprz))(H2O)2}4+ rods; mixed valence ![]()
clusters are embedded in the network. Compound 3, [Cu2(tpyprz){HO3P(CH2)3PO3H}][V2F2O5], consists of ![]()
chains and isolated {V2F2O5}2− anions. Structures 1–3 are compared to the structures of the analogous series ![]()
, where bisterpy is 2,2′:4′:4″:2″,2![]()
-quaterpyridine, 6′,6″-di-2-pyridinyl. The temperature-dependent magnetic susceptibilities of 2 and 3 are also discussed.