Enzymatic ring opening polymerization of ω-pentadecalactone using supercritical carbon dioxide
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- 作者：André ; E. Polloni ; Josamaique G. Veneral ; Evertan A. Rebelatto ; Dé ; bora de Oliveira ; J. Vladimir Oliveira ; Pedro H.H. Araú ; jo ; Claudia Sayer ; claudia.sayer@ufsc.br" class="auth_mail" title="E-mail the corresponding author
- 关键词：Polymerization ; Novozym 435 ; ω-pentadecalactone ; Supercritical carbon dioxide
- 刊名：The Journal of Supercritical Fluids
- 出版年：2017
- 出版时间：January 2017
- 年：2017
- 卷：119
- 期：Complete
- 页码：221-228
- 全文大小：1559 K
文摘
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Enzymatic polymerization of ω-pentadecalactone.
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Reactions conducted in a variable volume-view reactor.
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Supercritical carbon dioxide as solvent and different co-solvents.
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Mass ratio of monomer/solvent/co-solvent influenced reaction yield and molecular weight.
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Water content on enzyme has influence in molecular weight of poly(ω-pentadecalactone).