A new cycloadduct based on quadricyclane and perfluorocyclohexene: synthesis, metathesis polymerization and gas-transport properties of the obtained polymer

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• 作者：Ilya L. Borisov ; Timur R. Akmalov ; Andrey O. Ivanov ; Vladimir V. Volkov ; Eugene Sh. Finkelshtein ; ^{fin314@gmail.com" class="auth_mail" title="E-mail the corresponding author} ; Maxim V. Bermeshev ; ^{bmv@ips.ac.ru" class="auth_mail" title="E-mail the corresponding author}
• 刊名：Mendeleev Communications
• 出版年：2016
• 出版时间：March-April 2016
• 年：2016
• 卷：26
• 期：2
• 页码：124-126
• 全文大小：205 K

文摘

A new fluorine-containing tricyclononene was synthesized by [2σ + 2σ + 2π]-cycloaddition of quadricyclane with perfluorocyclohexene. This cycloadduct was subjected to ring-opening metathesis polymerization. Gas-transport properties of the obtained polymer were estimated.