Unexpected “reverse‿cyclization of 2-mercaptobenzimidazole with chlorotrifluoroethylene and hexafluoropropene
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- 作者：Kirill I. Petko ; kirpet@ukr.net" class="auth_mail" title="E-mail the corresponding author ; Yurii G. Vlasenko ; Oleksii D. Kachkovskii
- 关键词：2-Mercaptobenzimidazole ; Chlorotrifluoroethylene ; Hexafluoropropene ; Single crystal X-ray diffraction analysis
- 刊名：Journal of Fluorine Chemistry
- 出版年：2016
- 出版时间：May 2016
- 年：2016
- 卷：185
- 期：Complete
- 页码：168-172
- 全文大小：455 K
文摘
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The unusual behavior of fluorinated alkenes was observed.
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New fluorinated hererocycles - benzimidazo[4,5b]thiazoles-1,3 were isolated.
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The structures were supported by X-ray diffraction.
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The possible reaction route was proposed.