data analysis was analyzed by Voigt deconvolution method.
each spectral line consists of a superposition of two bands.
Competition between the Gaussian and the Lorentzian width was evident in figures (5,6,7).
The width ratio () reveals the issue of competition between thermal and collisional effects.
Voigt FWHM was always a linear function with the pressure at 298 K, 323 k and 348 K, but at 373 K does not.