A study of competitive molecular interaction effects on imprinting of molecularly imprinted polymers
详细信息    查看全文
文摘
The work herein reports on an approach to obtain molecularly imprinted polymers (MIPs) for Atmer 129, an antistatic added to polyolefins and a previously non imprinted template with intra molecular H-bonding capability. The template-monomer interactions occurring in pre- and post-polymerization media were analyzed by FTIR and ATR-FTIR, respectively. After the prepolymerization study, the synthesis conditions were discussed and suitable porogens and potential template:monomer stoichiometries were suggested. The imprinting efficiency and selectivity of MIPs were evaluated in batch assays by HPLC or UPLC and compared with thermal behavior and morphological characteristics checked by Thermogravimetric Analysis (TGA), Differential Scanning Calorimetry (DSC) and Scanning Electron Microscopy (SEM). The best results were obtained for MIPs synthesized at 60 ¡ãC. A relation between imprinting effect and template shape recognition was suggested by selectivity studies. The major conclusion, which has been drawn from FTIR and DSC studies, is that independently of the H-bonding strength between Atmer 129 and monomer, the template started to crystallize out during the polymerization reaction, thus reducing the imprinting effect.

© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号

地址:北京市海淀区学院路29号 邮编:100083

电话:办公室:(+86 10)66554848;文献借阅、咨询服务、科技查新:66554700