文摘
In this paper, we investigate the half-metallicity of Heusler alloys Fe2Co1?xCrxSi by first principles calculations and anisotropy magnetoresistance measurements. It is found that, with the increase of Cr content x, the Fermi level of Fe2Co1?xCrxSi moves from the top of valence band to the bottom of conduction band, and a large half-metallic band gap of 0.75 eV is obtained for x=0.75. We then successfully synthesized a series of Heusler Fe2Co1?xCrxSi polycrystalline ribbon samples. The results of X-ray diffraction indicate that the Fe2Co1?xCrxSi series of samples are pure phase with a high degree of order and the saturation magnetic moment follows half-metallic Slater-Pauling rule. Except for the two end members, Fe2CoSi and Fe2CrSi, the anisotropic magnetoresistance of Fe2Co1?xCrxSi (x=0.25, 0.5, and 0.75) shows a negative value suggesting they are stable half-metallic ferromagnets.