Aerobic oxidation of secondary alcohols in water with ABNO/tert-butyl nitrite/KPF₆ catalytic system

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• 作者：Jiaqi Ma ; Chao Hong ; Yan Wan ; Meichao Li ; Xinquan Hu ; Weimin Mo ; Baoxiang Hu ; Nan Sun ; Liqun Jin ; Zhenlu Shen ; ^{zhenlushen@zjut.edu.cn}
• 关键词：Oxidation ; ABNO ; Secondary alcohols ; Oxygen ; Water
• 刊名：Tetrahedron Letters
• 出版年：2017
• 出版时间：15 February 2017
• 年：2017
• 卷：58
• 期：7
• 页码：652-657
• 全文大小：1521 K
• 卷排序：58

文摘

Oxidation of secondary alcohols into ketones. ABNO, tert-butyl nitrite and KPF6 as the catalysts and oxygen as the oxidant. Good to excellent yields can be obtained. Water as the green reaction solvent. Metal-free reaction conditions.