Reaction pathways for selective oxidation of propane to acrolein over Ce-Ag-Mo-P-O catalysts

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• 作者：Xin Zhang ; Huilin Wan ; Weizheng Weng
• 关键词：Selective oxidation ; Propane ; Acrolein ; Intermediate ; Reaction pathways
• 刊名：Applied Catalysis A: General
• 出版年：2009
• 出版时间：31 January 2009
• 年：2009
• 卷：353
• 期：1
• 页码：24-31
• 全文大小：1057 K

文摘

The reaction pathways for selective oxidation of propane to acrolein on Ce_0.1Ag_0.3Mo_0.5P_0.3O_x catalyst were investigated by three methods, (i) steady-state reaction test of the individual oxidation of propane and the probe molecule of possible reaction intermediates, (ii) temperature-programmed surface reaction (TPSR) study of propane oxidation in presence of gas phase O₂ or not, and (iii) in situ Raman spectroscopy investigation of propane oxidation and propylene oxidation on the catalyst. Based on the obtained results, three possible reaction pathways for selective oxidation of propane to acrolein on the catalysts are proposed. The major reaction pathway is that propylene (π-allyl species) is produced from the activation of the methylene C–H bond of propane and further oxidizes to acrolein through σ-allyl species. However, the presence of gas phase O₂ favors the formation of acrolein in propane oxidation on the catalyst.