Synthesis and characterization of a 4-nitrophenyl functionalized NHC ligand and its palladium(II) complex
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- 作者：Fatemeh Rajabi ; Jens Trampert ; Yu Sun ; Mark Busch ; Stefan Br?se ; Werner R. Thiel
- 关键词：NHC ligand ; Palladium ; Nitro groups ; X-ray structure
- 刊名：Journal of Organometallic Chemistry
- 出版年：2013
- 出版时间：1 November, 2013
- 年：2013
- 卷：744
- 期：Complete
- 页码：101-107
- 全文大小：955 K
文摘
The synthesis and characterization of a novel pyridine coordinated dichloridopalladium(II) NHC complex is described. This compound possesses a saturated NHC ligand that is substituted with a para-nitrophenyl function in the 4-position of the NHC backbone. It is accessible in four steps with overall good yields starting from 4-nitro acetophenone.