Functionalised [(NHC)Pd(allyl)Cl] complexes: Synthesis, immobilisation and application in cross-coupling and dehalogenation reactions
详细信息 查看全文
- 作者：John-Michael Collinson ; James D.E.T. Wilton-Ely ; j.wilton-ely@imperial.ac.uk" class="auth_mail" title="E-mail the corresponding author ; Silvia Dí ; ez-Gonzá ; lez ; s.diez-gonzalez@imperial.ac.uk" class="auth_mail" title="E-mail the corresponding author
- 关键词：Cross-coupling ; Dehalogenation ; N-Heterocyclic carbene ; Palladium complexes ; Transfer hydrogenation
- 刊名：Catalysis Communications
- 出版年：2016
- 出版时间：5 December 2016
- 年：2016
- 卷：87
- 期：Complete
- 页码：78-81
- 全文大小：1443 K
文摘
- •
A novel [(NHC)PdII] unit has been immobilised on silica coated nanoparticles.
- •
Good activity shown in Suzuki-Miyaura and chloroarene dehalogenation reactions.
- •
Pd-mediated transfer hydrogenation of carbonyl compounds is demonstrated