Functionalised dithiocarbamate complexes: Synthesis and molecular structures of 2-diethylaminoethyl and 3-dimethylaminopropyl dithiocarbamate complexes [M{S2CN(CH2CH2N
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- 作者：Graeme Hogarth ; Ebony-Jewel C.-R.C.R. Rainford-Brent ; Shariff E. Kabir ; Idris Richards ; James D.E.T. Wilton-Ely ; Qi Zhang
- 关键词：Dithiocarbamate ; Crystal structures ; Amine ; Functionalised
- 刊名：Inorganica Chimica Acta
- 出版年：2009
- 出版时间：20 April 2009
- 年：2009
- 卷：362
- 期：6
- 页码：2020-2026
- 全文大小：325 K
文摘
The amine-functionalised dithiocarbamate salts K[S2CN(CH2CH2NEt2)2] and K[S2CN(CH2CH2CH2NMe2)2] have been prepared and used for the synthesis of a number of bis and tris-dithiocarbamate complexes. The molecular structures of five of these namely, [M{S2CN(CH2CH2NEt2)2}2] (M = Cu, Ni), [M{S2CN(CH2CH2CH2NMe2)2}2] (M = Cu, Pd) and [Co{S2CN(CH2CH2CH2NMe2)2}3], have been elucidated by X-ray crystallography.