In numerical simulations of coal combustion processes, particle-radiation interaction is often described by Mie-theory. An important modeling assumption in Mie-theory is the sphericity of the particles. The aim of this study is to investigate the validity of the sphericity assumption. Therefore, the T-Matrix method is applied to calculate the scattering and absorption properties of non-spherical particles and to compare these with results from Mie-theory. Three types of non-spherical particles are considered: prolate, oblate, and Chebychev-type particles. The scattering and absorption properties are averaged over a particle size distribution, the incident radiation
profile, and for non-spherical particles a particle orientation distribution.
The calculations reveal a deviation in scattering and absorption efficiencies below 10 % due to non-sphericity for all particles. For the scattering phase function, the deviation is on the order of 10 %. It strongly varies depending on the particle type under investigation. Nevertheless, Mie-theory can correctly predict trends. Taking into account several uncertainties in the input parameters for scattering calculations, Mie-theory can be applied in the prediction of scattering and absorption properties in numerical simulations of coal combustion.