Microstructural characteristics and degradation mechanism of the NiCrAlY/CrN/DSM11 system during thermal exposure at 1100 °C

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• 作者：Weizhou Li ; Yueqiao Li ; Chao Sun ; Zhiliu Hu ; Tianquan Liang ; Wuquan Lai
• 关键词：Coatings ; Diffusion barrier ; Interdiffusion ; Oxidation-resistance ; Microstructure
• 刊名：Journal of Alloys and Compounds
• 出版年：2010
• 出版时间：10 September 2010
• 年：2010
• 卷：506
• 期：1
• 页码：77-84
• 全文大小：1013 K

文摘

To limit the elemental interdiffusion, a CrN diffusion barrier was introduced into the interface of NiCrAlY overlayer and DSM11 substrate. During vacuum heat treatment and thermal exposure, the single and continuous CrN barrier layer was first changed to the multilayer structure and then to the Ti-rich interlayer. With the gradual loss of continuity in the diffusion barrier, the elemental interdiffusion was accelerated. Due to the interdiffusion, the transformation of β-NiAl → γ′-Ni₃Al → γ-Ni and the low Al level occurred in the overlayer. The phase transformation of metastable θ-Al₂O₃ to stable α and the accelerated elemental interdiffusion affected the integrity of the surface scales. After 100 h exposure at 1100 °C, the Al element was insufficient and the duplex coatings were degraded.