HPW/MCM-41 catalyzed isomerization and dimerization of pure pinene and crude turpentine
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- 作者：Genkuo Nie ; Ji-Jun Zou ; jj_zou@tju.edu.cn" class="auth_mail ; Ren Feng ; Xiangwen Zhang ; Li Wang
- 关键词：Pinene ; Turpentine ; Dimerization ; Isomerization ; HPW/MCM-41
- 刊名：Catalysis Today
- 出版年：1 October 2014
- 年：2014
- 卷：234
- 期：Complete
- 页码：271-277
- 全文大小：1370 K
文摘
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伪-Pinene, 尾-pinene and crude turpentine give similar product distribution in isomerization/dimerization.
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Dimerization involves a quick isomerization and the dimers are formed from isomeric compounds.
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Crude turpentine can be used to produce chemicals that are generally formed from pure pinenes, suggesting an efficient and cheap way for turpentine utilization.
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HPW/MCM-41 is more active than bulk HPW and HPW/Al-MCM-41.