Thermogravimetric analysis of MSW pyrolysis and combustion were studied.
The additives (ZnO, Fe2O3 and Al2O3) facilitated the pyrolysis and combustion of MSW.
The additive CuO prohibited the decomposition and combustion of biowaste matter.
High oxygen concentration provided more help in combustion of MSW.
Kinetic parameters were calculated to appraise the pyrolysis and combustion of MSW.