A novel dimeric polyanion based on mono-manganese substituted Keggin-type phosphotungstate: (MnPW11O39)210 ∿/sup>
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- 作者：Xinbo Dong ; Shenghua Yang ; Bin Liu ; Panfeng Wu ; Huaiming Hu ; Ganglin Xue ; xglin707@163.com" class="auth_mail" title="E-mail the corresponding author
- 关键词：Polyoxometalate ; Polyanion ; Phosphotungstate ; Transition metal substituted
- 刊名：Inorganic Chemistry Communications
- 出版年：2016
- 出版时间：June 2016
- 年：2016
- 卷：68
- 期：Complete
- 页码：76-79
- 全文大小：536 K
文摘
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A novel dimeric phosphotungstate based on mono-substituted Keggin-type has been synthesized.
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The dimeric polyanion is linked by two TM-μ2-O-TM bridges.
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The antiferromagnetic interactions exist among the Mn·Mn ions.