A novel mechanism for the oxidation reaction of VO2+ on a graphite electrode in acidic solutions
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- 作者：Wenjun Wang ; Xinzhuang Fan ; xzfan@imr.ac.cn" class="auth_mail ; fanjianghao521@163.com" class="auth_mail ; Jianguo Liu ; Chuanwei Yan ; Chaoliu Zeng
- 关键词：Vanadium ; Reaction mechanism ; Kinetic equation ; Rotating disk system ; Carbon electrodes
- 刊名：Journal of Power Sources
- 出版年：1 September 2014
- 年：2014
- 卷：261
- 期：Complete
- 页码：212-220
- 全文大小：1932 K
文摘
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The reaction orders of VO2+ and H+ for the oxidation reaction of VO2+ are calculated.
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A new reaction mechanism is proposed to describe the oxidation of VO2+.
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A real kinetic equation is built up for the oxidation reaction of VO2+.